The art of
garment dyeing is an ancient one. There is evidence that prehistoric man
applied colored pigments to vegetable & animal matter such as fibers &
skins. Garments made from various fabrics are now being dyed & delivered to
the customer in a short period of time. With today’s exploding clothing markets
of casual & sportswear, garment dyeing has emerged as one of the better
production routes towards meeting the quickly changing demands of the fashion
market. Though any kind of material can be dyed in garment from but cotton is
more popular to dye and finish in garment form than any other fibre. Processing
of DENIM and some CHINOES is more common fashion in garment dyeing field.
Denim goods
finishing has a longer history, the techniques used for denim finishing has
been extended to other items such as chambrays, solid color indigo dyed fabrics
& chinoes suiting. A variety of washing effects are achievable on denim
goods dyed with the traditional indigo dyed, which is selected on accounts of
it’s brilliant blue color & excellent fading characteristics to washing,
finishing or abrasion. Depending upon the dyeing method, goods dyed with indigo
dyes have poor color penetration with ring dyed yarns; thus after finishing
them they give good acceptable faded look.
Some of the
most popular common & advanced washing & finishing techniques for denim
garments & others are given below.
1)
CONVENTIONAL
WASHING :
This
entails the desizing the materials with enzyme & detergent followed by
washing at an elevated temperature. The degree of color fading is comparatively
slight, but uniform.
2)
STONE
WASHING :
Volcanic
rocks also called as PUMICE stones are added to the garments during washing as
abradant. Colour fading by this process is more but not uniform. The degree of
color fading depends upon washing time and stone ratio (i.e. Wt. of stones: Wt.
of Garments), size of stones, liquor ratio & garment load. Generally
washing machine is run for 60 min. to 120 min. & it depends upon degree of
fading.
3)
DENIM
BLEACHING :
In
this process a strong oxidative bleach such as Sodium hypochlorite or Potassium
permanganate is added during washing, with or without stone addition.
Discoloration is usually more apparent depending on strength of the bleaches, liquor quantity and treatment
time. A strong bleach with short treatment time is preferred for better
bleached colors. The bleached goods should be adequately anticlored or after
washed with peroxide to minimize subsequently yellowing & tendering of the
goods. Some times optical brightening agent is added to get brighter appearance
for white or near white shades.
A recent innovation in decolorizing
Indigo, referred to as enzyme bleaching using LACCASE enzyme(Mediator system). Laccase is an Oxidoreductase enzyme that accepts oxygen from air & attaches
it to a mediator, which then reacts & decolorizes the indigo molecule. The
mediator, which is an organic molecule, consumed during 10 – 20 min. period so
the process is self limiting without any degradation or weakening of the
product or no danger of over bleaching.
Color can also be removed in denim washing
by reductive processes. One process, some times called Sugar bleaching, uses
carbohydrates like Dextrose, which contain reducing groups. The process
requires high pH, elevated temperature & large quantity of Carbohydrates.
The use of high level of Carbohydrates produces waste water & high BOD
& COD.
4)
ACID
WASHING ( STONE WASH) :
Acid
washing is usually done by tumble drying the garments with Pumice stones
presoaked in a solution of Sodium hypochlorite (5 – 10%) or potassium
permanganate (3 – 6%) such that localized bleaching takes place resulting in a
non-uniform sharp Blue/ White contrast. The color contrast after tumbling can
be further enhanced by a subsequent optical brightening. Soft stones that are
usually dust off are suitable for this process.
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